feat: migrate to Postgres + pgvector with Alembic scaffolding

Switch the default database from SQLite to Postgres + pgvector (via
pgvector/pgvector:pg16 Docker image) to support the upcoming vision
pipeline (embeddings, OCR, object detection, face clustering).

- Add `db` service to docker-compose.yml with healthcheck
- Wire `alembic upgrade head` into backend CMD before uvicorn
- Bootstrap empty 0001_baseline revision (schema still owned by create_all)
- Guard SQLite-only PRAGMAs and inline ALTERs behind _is_sqlite flag
- Run `CREATE EXTENSION IF NOT EXISTS vector` on Postgres init
- Add asyncpg, psycopg2-binary, pgvector to requirements
- Provide docker-compose.sqlite.yml escape hatch for legacy SQLite mode

Fresh DB + rescan assumed — no SQLite→Postgres data migration.

Co-Authored-By: Claude Opus 4.6 (1M context) <noreply@anthropic.com>

backend/alembic/script.py.mako

@@ -0,0 +1,26 @@
+"""${message}
+
+Revision ID: ${up_revision}
+Revises: ${down_revision | comma,n}
+Create Date: ${create_date}
+
+"""
+from typing import Sequence, Union
+
+from alembic import op
+import sqlalchemy as sa
+${imports if imports else ""}
+
+# revision identifiers, used by Alembic.
+revision: str = ${repr(up_revision)}
+down_revision: Union[str, None] = ${repr(down_revision)}
+branch_labels: Union[str, Sequence[str], None] = ${repr(branch_labels)}
+depends_on: Union[str, Sequence[str], None] = ${repr(depends_on)}
+
+
+def upgrade() -> None:
+    ${upgrades if upgrades else "pass"}
+
+
+def downgrade() -> None:
+    ${downgrades if downgrades else "pass"}